Facile synthesis of sulfide Bi13S18I2 as a promising anode material for a lithium-ion battery

被引：1
|
作者：
Yang, Cheng-Lu [1 ]
Liang, Chen [1 ]
Gao, Chao [1 ,2 ]
Guo, Jun [1 ,2 ]
Chen, Bu-Ming [1 ,2 ,3 ]
Huang, Hui [1 ,2 ,3 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Peoples R China
[2] Res Ctr Met Electrode Mat Engn Technol, Kunming 650106, Peoples R China
[3] Kunming Hendera Sci & Technol Co Ltd, Kunming 650106, Peoples R China
来源：
RSC ADVANCES | 2023年 / 13卷 / 41期
基金：
中国国家自然科学基金;
关键词：
GRAPHENE OXIDE COMPOSITE; NEGATIVE ELECTRODES; CARBON; BI2S3; SPHERES;
D O I：
10.1039/d3ra04845d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel Bi13S18I2 structure was synthesized using a facile one-pot hydrothermal method and further optimized as an anode material using graphene. The graphene/Bi13S18I2 composite achieved a high discharge capacity with an initial value of 1126.5 mA h g(-1) and a high and stable discharge capacity of 287.1 mA h g(-1) after 500 cycles compared with pure Bi13S18I2, which derives from the inhibited volume expansion and high electrical conductivity obtained from graphene. In situ XRD was performed to analyze the Li storage mechanism in depth. The results support the feasibility of the new ternary sulfide Bi13S18I2 as a promising lithium ion battery.
引用
收藏
页码：28389 / 28394
页数：6
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