Investigating Electrode-Ionomer Interface Phenomena for Electrochemical Energy Applications

The endeavor to develop high-performance electrochemical energy applications has underscored the growing importance of comprehending the intricate dynamics within an electrode's structure and their influence on overall performance. This review investigates the complexities of electrode-ionomer interactions, which play a critical role in optimizing electrochemical reactions. Our examination encompasses both microscopic and meso/macro scale functions of ionomers at the electrode-ionomer interface, providing a thorough analysis of how these interactions can either enhance or impede surface reactions. Furthermore, this review explores the broader-scale implications of ionomer distribution within porous electrodes, taking into account factors like ionomer types, electrode ink formulation, and carbon support interactions. We also present and evaluate state-of-the-art techniques for investigating ionomer distribution, including electrochemical methods, imaging, modeling, and analytical techniques. Finally, the performance implications of these phenomena are discussed in the context of energy conversion devices. Through this comprehensive exploration of intricate interactions, this review contributes to the ongoing advancements in the field of energy research, ultimately facilitating the design and development of more efficient and sustainable energy devices. This review explores complexities of electrode-ionomer interactions, crucial for optimizing electrochemical interface for high-performance in electrochemical energy devices. Our examination in both microscopic and meso/macro scale shows how these interactions affect surface reaction by changing reaction kinetics and oxygen/proton transport. State-of-the-art techniques for studying ionomer distribution are also presented. Moreover, performance implications for energy conversion and storage devices are highlighted.+ image