Intensified ClO2 Generation/Utilization Mechanism for the High-Gravity SO2/NO x Removal Process within a Rotating Packed Bed

被引:1
|
作者
Wu, Shao [1 ,2 ]
Lu, Zhicheng [3 ]
Duan, Xiaoxi [1 ]
Luo, Yong [4 ]
Chen, Yang [1 ]
Wang, Jiancheng [2 ]
Qian, Zhi [1 ,2 ]
机构
[1] Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China
[2] Binzhou Inst Technol, Binzhou City 256606, Shandong, Peoples R China
[3] Drexel Univ, Coll Engn, Dept Chem & Biol Engn, Philadelphia, PA 19104 USA
[4] Beijing Univ Chem Technol, Res Ctr, Minist Educ High Grav Engn & Technol, Beijing 100029, Peoples R China
关键词
NITRIC-OXIDE; FLUE-GAS; ELEMENTAL MERCURY; IDENTIFICATION; REACTOR; NACLO2; SYSTEM; MODEL; NO;
D O I
10.1021/acs.iecr.3c00726
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Unlikethe traditional acid-catalyzed chlorine dioxide (ClO2)generation technology, this study proposes an intensifiedClO(2) generation/utilization mechanism based on rotatingpacked bed (RPB)-enhanced NaClO2 synergistic removal ofsulfur dioxide (SO2) and nitrogen oxides (NOx). The essential of the intensification mechanism is the renewalof a gas-liquid interface caused by the high-gravity environmentin RPB. A theoretical model based on the penetration theory is derivedto evaluate the mechanism. Then, based on the mechanism, a cost-efficientmethod is developed for the synergistic removal process of SO2/NOx. The results indicated that the removal ratesfor SO2 and NOx reached 100% and 91.1%. respectively,under optimal conditions. To simulate the coupling effects of theoperating variables and find the optimal conditions for the process,a T-S-based fuzzy model is established. The error of the fuzzymodel is within & PLUSMN;12%, which proves its reliability for prediction.
引用
收藏
页码:11236 / 11247
页数:12
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