Identifying susceptible groundwater contamination zones in western Odisha of India using hydro-geochemical and geospatial approaches

Nuapada is one of the most drought-affected and fluoride-contaminated districts in Odisha, India. The presence of various dissolved substances, evapotranspiration, and lowering water table during pre- and post-monsoon (PRM and POM) seasons are responsible for declining groundwater (GW) quality over the Nuapada region. To comprehend the contaminated GW zones over the Nuapada and Komna blocks of the northern Nuapada district during the seasons, integration of hydrogeochemistry and statistical approaches using GW sample data on a geospatial platform have been done. The analysis exhibits that the major source of groundwater contamination is mostly geogenic with little anthropogenic impact. The cumulative impact of fluoride (F-), iron (Fe2+), and nitrate (NO3-) contents are noticed in great-depth zones of the water table in the north and south parts of Nuapada and Komna blocks, respectively. The dominant hydro facies, such as Na-Cl (41.77%) and Ca-Cl (25.31%) types exist over both blocks during PRM and POM seasons, respectively. Demarcation of contaminant and susceptible zones over the study area using geospatial analysis and groundwater quality indices (GWQI) were done. About 3% of the total area, in the north and middle parts of the Nuapada and Komna blocks, falls under contamination zones and is unfit for drinking purposes, and about 35% of the region is susceptible to future contamination. The outcome of the result analysis will enhance the scope for researchers, policymakers, and water managers to regulate emerging health, agricultural, and industrial issues in the stressed aquifer system in India and the world.