Coupling of alloy chemistry, diffusion and structure by grain boundary engineering in Ni-Cr-Fe

The diffusion-microstructure correlations for grain boundaries (GBs) in the technologically-relevant Ni-based 602CA alloy are investigated. Prolonged annealing treatments up to 744 h create distinct GB complexions with specific segregation-precipitation-structure states. Globular M23C6-type carbides at straight GBs and plate-like carbides together with NiAl-enriched (y '-type) particles at hackly GBs are found to co-exist. Moreover, an atomic-scale GB spinodal-like decomposition, especially at straight GBs, is observed. The co-existence of the two distinct states of general high-angle GBs, indicated by tracer diffusion experiments and verified by a detailed structure examination, is explained via state-of-the-art measurements of local elastic strains. In a course of annealing at 873 K, the relatively "fast"diffusivities are found to increase by a factor of 10 or more as a result of a coupled evolution of the GB plate-like precipitates and the irregular GB structures, whereas the relatively "slow" diffusivites remained practically unchanged representing the contributions of straight interfaces with spherical precipitates. Thus, the diffusion properties of high-angle GBs evolve together with characteristic changes of GB complexions distinguished by a growth of carbide-and y '-type precipitates and a concomitant generation of GB dislocation networks. The obtained results provide novel insights into grain boundary tailoring by utilizing structure - kinetics correlations involving segregation, precipitation and the evolution of interface defects.