Comparative study on induction brazing of diamond with rare earth Nd-doped crystalline and amorphous Ni-based filler alloy

This essay aims to comparatively study the microscopic morphology and grinding properties of brazed diamonds with amorphous and crystalline filler alloy in the case of rare-earth Nd-doped modified Ni-based filler alloy. The results show that at the same content of Nd, Cr7C3 is mainly generated at the brazing interface of crystalline samples. In contrast, Cr27C6 is mainly generated at the brazing interface of amorphous samples. Amorphous solder material achieves a robust chemical metallurgical union, producing a dense and homogeneous carbide layer. The bonding strength between amorphous solder material and diamond is further enhanced. The addition of rare earth element Nd contributes greatly to the forming ability of amorphous filler alloy. Nd atoms in the amorphous solder material readily bond with Ni atoms, reducing the chemical corrosion of Ni atoms on diamonds and resulting in a lower degree of graphitization. When the amount of Nd added is 1.0 wt%, the morphology of amorphous filler alloy brazing diamond is more complete than the effect of the crystalline state, the degree of thermal damage is lower, and the surface of amorphous filler alloy brazing is smoother. Frictional wear experiments show that the amorphous filler alloy holds diamond better than the crystalline filler alloy, and the diamond specimens prepared with the amorphous filler alloy demonstrate a significantly superior grinding performance in comparison to the diamond specimens prepared with the crystalline filler alloy.