Synthesis and crystal structures of two solvates of 1-{[2,6-bis(hydroxymethyl)-4-methylphenoxy]-methyl}-3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]-methyl}-2,4,6-triethylbenzene

被引：1

作者：

Stapf, Manuel ^{[1
]}

Schmidt, Ute ^{[1
]}

Seichter, Wilhelm ^{[1
]}

Mazik, Monika ^{[1
]}

机构：

[1] Tech Univ Bergakad Freiberg, Inst Organ Chem, Leipziger Str 29, D-09599 Freiberg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

crystal structures; tripodal molecule; hydrogen bonding; C-H center dot center dot center dot pi and; pi-pi interactions; CARBOHYDRATE RECEPTORS; BEARING PYRAZOLE; BUILDING-BLOCK; RECOGNITION; AMINOPYRIDINE; CONFORMATIONS; PATTERNS; PYRIDINE;

D O I：

10.1107/S2056989023009155

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystal structures of the formamide monosolvate (1a) and the n-propanol/H2O solvate/hydrate (1b) of the title compound, C38H50N4O3 (1), the tripodal host molecule adopts a conformation in which the substituents attached to the central benzene ring are arranged in an alternating order above and below the ring plane. As a result of the different nature of the involved guest species, the crystal components in 1a create a three-dimensional supramolecular architecture, while the crystal structure of 1b consists of two-dimensional supramolecular aggregates extending parallel to the crystallographic ab plane.

引用

页码：1067 / +

页数：24

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