Quantitative analysis of naphthalene, 1-naphthol and 2-naphthol at nanomol levels in geothermal fluids using SPE with HPLC

被引:0
|
作者
Sajkowski, Lucjan [1 ]
Seward, Terry M. [2 ]
Mountain, Bruce W. [1 ]
机构
[1] GNS Sci, Dept Earth Resources & Mat, Wairakei, New Zealand
[2] Victoria Univ Wellington, Sch Geog Environm & Earth Sci, Wellington, New Zealand
关键词
Naphthalene; Naphthol; Chromatography; HPLC; SPE geothermal tracers; LIQUID-CHROMATOGRAPHY; HUMAN URINE; WATER; EXTRACTION; SAMPLES;
D O I
10.1016/j.mex.2023.102244
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Naphthalene (NAP), 1-naphthol (1-NAP) and 2-naphthol (2-NAP) are the thermal decomposition products of naphthalene sulfonates making them potentially new geothermal reservoir permeability tracers, however, to date, no sensitive and fast detection method for these compounds has been developed. In order to facilitate sensitive and rapid analysis of these compounds in geothermal brines and associated steam condensates, a high-performance liquid chromatography (HPLC) method combined with solid-phase extraction (SPE) has beendeveloped.A method for determination of naphthalene, 1-and 2-naphthol from brines has been developed.These compounds have been detected in steam samples from three New Zealand geothermal fields.As breakdown products of NDS/NSA, these compounds have potential use as geothermal tracers.
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页数:8
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