Frustrated radical pairs in selective functionalization of inert aliphatic C-H bonds

被引：2

作者：

Pramanik, Milan ^{[1
]}

Melen, Rebecca L. ^{[1
]}

机构：

[1] Cardiff Univ, Cardiff Catalysis Inst, Translat Res Hub, Maindy Rd, Cardiff CF24 4HQ, Wales

来源：

CHEM | 2023年 / 9卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

CLEAVAGE;

D O I：

10.1016/j.chempr.2023.07.012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this preview, we highlight Lin and co-workers' recent findings published in Nature on the non-directed functionalization of chemically inert aliphatic C H- bonds through the use of the hexamethyldisilazide anion (HMDS-, a reductant) and N-oxoammonium cation (TEMPO+, an oxidant) as a new class of frustrated radical pair.

引用

页码：2060 / 2062

页数：3

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