One-Pot, Metal-Free Synthesis of Phenols from Arylboronic Acids and Subsequent Conversion with N -Hydroxyphthalimide Esters

被引：0

作者：

Zhang, Zhigang ^{[1
]}

Ding, Di ^{[1
]}

Yang, Yiming ^{[1
]}

Wan, Ruiying ^{[2
]}

Gong, Lili ^{[2
]}

Guan, Haixing ^{[2
]}

Li, Wei ^{[1
]}

机构：

[1] Shandong Univ Tradit Chinese Med, Coll Pharm, Jinan 250355, Peoples R China

[2] Shandong Univ Tradit Chinese Med, Shandong Prov Key Lab Tradit Chinese Med, Key Lab Tradit Chinese Med Class Theory, Expt Ctr,Minist Educ, Jinan 250355, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2023年 / 55卷 / 14期

关键词：

tandem reactions; metal-free; TBHP; phenol; N -hydroxyphthalimide ester; GREEN-CHEMISTRY; ESTERIFICATION; WATER;

D O I：

10.1055/a-2044-9651

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot synthesis of phenyl esters between N-hydroxy-phthalimide (NHP) esters derived from carboxylic acid and arylboronic acids is developed. This tandem reaction underwent mild conditions with a broad range of substrates scope (up to 27 examples) in good to excellent yields (up to 93% yield). The reaction can be easily scaled up, which thus pave the way for further applications in late-stage modification.

引用

页码：2143 / 2150

页数：8

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