Advance of Dehydrogenation and Transfer Hydrogenation of Ammonia-Borane Catalyzed by Homogeneous Cobalt Complexes

被引：3

作者：

Liu Shuang ^{[1
,2
]}

Zou Lianghua ^{[1
]}

Wang Xiaoming ^{[2
]}

机构：

[1] Jiangnan Univ, Sch Life Sci & Hlth Engn, Wuxi 214122, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 43卷 / 05期

关键词：

ammonia borane; homogeneous catalysis; cobalt complex; dehydrogenation; transfer hydrogenation; DIMETHYLAMINE-BORANE; CHEMISTRY; MECHANISM; ALKYNES; DEHYDROPOLYMERISATION; SEMIHYDROGENATION; HYDROSILYLATION; ISOMERIZATION; AMINOBORANE; SILANES;

D O I：

10.6023/cjoc202302020

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As an ideal chemical hydrogen storage material, efficient dehydrogenation and transfer hydrogenation of ammonia borane has attracted increasing attention. Due to the advantages of cheap and easy availability and biocompatibility of earth-abundant metals, the development of homogeneous catalytic dehydrogenation and related transformation of ammonia borane with earth-abundant metals is a significant research topic in this field. Herein, the development of dehydrogenation and transfer hydrogenation of ammonia borane catalyzed by homogeneous cobalt complexes is reviewed.

引用

页码：1713 / 1725

页数：13

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