Microdroplet accelerated reaction for high-efficiency carbon disulfide conversion

被引：1
|
作者：
Gao, Yuanji [1 ]
Xia, Bing [2 ]
机构：
[1] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 72期
基金：
中国国家自然科学基金;
关键词：
ELECTRON; AMINES;
D O I：
10.1039/d3cc03503d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbon disulfide (CS2) negatively impacts male sexual function and sperm quality. We propose an efficient method to convert CS2 into dithiocarbamic acid using electrospray ionization, achieving up to 96.7% conversion. Protonated CS2 intermediates (S(sic)C(sic)SH+) contribute to capturing CO2 in amine reactions. Moreover, the reaction efficiently converts CS2 from ethanol solution using microbubble bursting. This study lays the groundwork for accurate CS2 detection.
引用
收藏
页码：10773 / 10776
页数：4
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