Comprehensive performance analysis and structural improvement of latent heat thermal energy storage (LHTES) unit using a novel parallel enthalpy-based lattice Boltzmann model

Latent heat thermal energy storage (LHTES) utilizing phase change material (PCM) is one of the critical enablers in developing sustainable and low-carbon energy systems. To fill the knowledge gap, this paper presents an enthalpy-based solid-liquid model through the lattice Boltzmann method (LBM) with a multi-relaxation-time (MRT) approach, aiming to simulate convective phase change in LHTES units with and without porous media in Cartesian or axisymmetric domains. To improve accuracy and efficiency, the model integrates a differential scanning calorimetry (DSC) correlated equation for enthalpy modeling, couples with a 1D heat-transfer-fluid (HTF) model for boundary treatment of HTF side, and employs a parallel LBM scheme for efficient parametric studies. The validation demonstrates the model's success in predicting PCM phase change, with errors below 10%. A comprehensive numerical analysis is then conducted to quantitatively evaluate the effect of convection on PCM melting. Novel metrics, such as acceleration rates (ac) of PCM melting and threshold Rayleigh numbers (Radc) at various aspect ratios, are introduced. Furthermore, PCM melting in the porous cylindrical unit is explored. Findings reveal up to 86% acceleration in melting compared to pure PCM at 80% energy storage, and the porous media with porosity above 0.9 is recommended for thermal enhancement. Moreover, this paper analyzes the negative effect of uneven temperature distributions caused by convection on LHTES unit efficiency. A modified LHTES unit geometry is proposed to offset this negative effect, and the study demonstrates successful mitigation of uneven temperature distributions, achieving up to 57 % acceleration in PCM melting.