Reactivity of Radical Anions and Dianions of Organic Compounds: A Review

被引：0
|
作者：
Mendkovich, A. S. [1 ]
Rusakov, A. I. [2 ]
机构：
[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow, Russia
[2] Demidov State Univ Yaroslavl, Yaroslavl, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2023年 / 59卷 / 12期
关键词：
radical anion; dianion; electroreduction; quantum-chemical calculations; dimerization; protonation; bond cleavage; DISSOCIATIVE ELECTRON-TRANSFER; HOMOGENEOUS REDOX CATALYSIS; TEMPERATURE IONIC LIQUIDS; MOLECULAR-ORBITAL THEORY; ALKALI-METAL CATIONS; ELECTROCHEMICAL DIMERIZATION REACTIONS; REGIOSELECTIVE BOND-CLEAVAGE; AROMATIC CARBOXYLIC-ACIDS; RING-DISK ELECTRODE; CURRENT-TIME CURVES;
D O I：
10.1134/S1023193523120078
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The results of experimental and theoretical studies of reactions involving pi*-radical anions and pi*-dianions are analyzed. Particular attention is paid to their role in electrochemical reduction processes. By the example of three most typical reactions for these particles, the main factors determining their reactivity are considered.
引用
收藏
页码：999 / 1031
页数：33
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