Preparation of GO-SiO2 three-dimensional point-plane nanomaterials and enhancement of epoxy resin mechanical property

被引:5
|
作者
Hao, Qiguo [1 ]
Zhang, Xu [1 ,6 ]
Liu, Shuang [2 ,3 ]
Peng, Hongjun [4 ]
Zhang, Pengyu [5 ]
Yu, Shengyang [4 ]
Mao, Zhiyi [5 ]
机构
[1] Hebei Univ Technol, Hebei Prov Key Lab Funct Polymers, Key Lab Funct Polymers Hebei Prov, Tianjin, Peoples R China
[2] Beijing Bldg Mat Acad Sci Res, Acad Low Carbon Concrete, Beijing, Peoples R China
[3] Beijing Bldg Mat Acad Sci Res, Solid Waste Reuse Bldg Mat State Key Lab, Beijing, Peoples R China
[4] Dachang BBMG Coating Co Ltd, Technol Res & Dev Dept, Langfang, Peoples R China
[5] Tianjin Bldg Mat Sci Res Acad Co Ltd, Res & Dev Ctr, Tianjin, Peoples R China
[6] Hebei Univ Technol, Hebei Prov Key Lab Funct Polymers, Tianjin 300401, Peoples R China
关键词
click chemistry; epoxy resin; GO; mechanical property; three-dimensional point plane; MODIFIED SILICA NANOPARTICLES; GRAPHENE OXIDE; THERMAL-PROPERTIES; PERFORMANCE; COMPOSITES; NANOCOMPOSITES; NANOSHEETS; CHAINS; AGENT;
D O I
10.1002/pc.27851
中图分类号
TB33 [复合材料];
学科分类号
摘要
In this research, mercapto-anchoring graphene oxide (GO) and epoxy-anchoring SiO2 nanoparticles (NPs) were assembled by mercapto-epoxy click chemistry to form three-dimensional (3D) point-plane structure nanomaterials (GO-SiO2), and epoxy resin (EP) composites were prepared using the auxiliary thermal blending method. The relationships among surface interfacial interaction, dispersion, and mechanical properties of composites were systematically investigated. The Research finding shows that SiO2 NPs covalently bonding with GO increases interface compatibility and dispersion, which explains epoxy composite strengthening. Compared to epoxy resin, 0.1 wt% GO-SiO2/EP composite has 38.65%, 36.15%, 44.64%, and 61.61% higher tensile strength, flexural strength, flexural modulus, and impact strengths. The enhancement mechanism of GO-SiO2 toward EP was analyzed.
引用
收藏
页码:1266 / 1277
页数:12
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