Synthesis of α-aryl ketones through transition-metal-free cross-coupling

被引：0
|
作者：
Li, Xue [1 ]
Song, Qiuling [1 ]
机构：
[1] Huaqiao Univ, Xiamen, Peoples R China
来源：
NATURE SYNTHESIS | 2023年 / 2卷 / 12期
关键词：
D O I：
10.1038/s44160-023-00374-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A strategy for the transition-metal-free C(sp2)-C(sp3) cross-coupling of alpha-(pseudo)halo aliphatic ketones and arylboronic acids via a 1,4-metallate shift is demonstrated. The reaction proceeds under mild conditions in the presence of base, and offers an operationally simple method for the construction of C(sp2)-C(sp3) bonds.
引用
收藏
页码：1138 / 1139
页数：2
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