High-Performance Organic Photosynaptic Transistors Using Donor-Acceptor Type and Crosslinked Core-Shell Nanoparticles as a Floating Gate Electret

Photosynaptic transistor is considered to be a potential candidate for breaking the von Neumann bottleneck in photo-communication field. Herein, a series of donor-acceptor type and crosslinked core-shell nanoparticles are designed and applied in phototransistors as a charge-trapping electret. The outer shell is composed of poly(ethylene glycol) methyl ether methacrylate (PEGMA); while the inner core comprises donors of thiophene and bithiophene (2T) and acceptors of benzothiazole (BT), naphthalenediimide (NDI), and hexafluorobenzene-naphthalenediimide (FB-NDI). It is found that the core-shell and donor-acceptor design play an important role in the charge trapping, photoresponse, and the corresponding device performance. Accordingly, the phototransistor comprising the crosslinked core-shell nanoparticles with a donor of 2T and an acceptor of BT (PV2T-BT) produced the highest memory ratio of 10(5) over 10(4) s at a high operating voltage of -40 V. Meanwhile, the same device presented the highest paired-pulse facilitation ratio of 168% at a medium operating voltage of -1 V, and an ultra-low energy consumption of 0.0324 fJ at a low operating voltage of -1 mu V. The findings in this study provide a new perspective on material design for phototransistor devices.