Solid-state NMR Spectroscopy of Iodine(I) Complexes

被引：4

作者：

Ward, Jas S. ^{[1
]}

Sievanen, Elina I. ^{[1
]}

Rissanen, Kari ^{[1
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, Jyvaskyla 40014, Finland

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 06期

基金：

芬兰科学院;

关键词：

solid-state NMR; halogen bond; iodine(I); Barluenga reagent; cation exchange; NUCLEAR-MAGNETIC-RESONANCE; HALOGEN; CAPSULES; REAGENTS; C-13;

D O I：

10.1002/asia.202201203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-state NMR has been applied to a series of Barluenga-type iodine(I) [L-I-L]PF6 (L=pyridine, 4-ethylpyridine, 4-dimethylaminopyridine, isoquinoline) complexes as their hexafluorophosphate salts, as well as their respective non-liquid ligands (L), their precursor silver(I) complexes, and the respective N-methylated pyridinium and quinolinium hexafluorophoshate salts. These results are compared and contrasted to the corresponding solution studies and single-crystal X-ray structures. As the first study of its kind on the solid-state NMR behavior of halogen(I) complexes, practical considerations are also discussed to encourage wider utilization of this technique in the future.

引用

页数：6

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