Chloroplast-granum inspired phase change capsules accelerate energy storage of packed-bed thermal energy storage system

Packed-bed thermal energy storage (PBTES) systems utilizing phase change capsules have found extensive applications in thermal energy harvesting and management to alleviate energy supply-demand imbalances. Nevertheless, the sluggish thermal charging rate of phase change materials (PCMs) capsules remains a significant impediment to the rapid advancement of PBTES. Here, bionic PCMs capsules are proposed by mimicking the internal and external structure of chloroplast-granum. The heat transfer and flow characteristics of the bionic PCMs capsules in the packed-bed are analyzed by experiments and numerical simulations. The results illustrate that the chloroplast-fin type PCMs capsule exhibits significantly faster heat storage compared to the sphere type PCMs capsule. This improvement is attributed to the bionic folded shape and inner membrane structure, which generate multiple local vortices to enhance heat convection, and shorten the heat transfer distance between the capsule wall and center PCMs to facilitate heat conduction. The PCMs capsules are further filled into the packedbed in a staggered arrangement, resulting in increased heat transfer area and enhanced disturbance flow as compared to an aligned arrangement. Consequently, the melting time of the packed-bed filled with chloroplastfin type capsules is reduced by 33.2%, meanwhile the average exergy storage rate and exergy efficiency are enhanced by 48.4% and 8.3%, respectively, compared to the packed-bed filled with sphere type capsules. This research offers a novel approach for designing high-performance PBTES system utilizing bionic capsules.