A Self-Crystallized Nanofibrous Ni-GDC Anode by Magnetron Sputtering for Low-Temperature Solid Oxide Fuel Cells

The optimum composition ratio of the anode cermet (Ni-GDC) for solid oxide fuel cells (SOFCs) varies because the electron-collecting mechanism is different depending on its applications. A Co-sputtering method facilitates ratio control with sputtering power adjustment. However, there is a practical issue with fabricating anode cermet with various ratios attributed to the large sputtering yield gap of the metal target, Ni, and the ceramic target, gadolinia-doped ceria (GDC). Therefore, in this study, a Gd-Ce metal alloy was applied instead of GDC to match the sputtering rate with that of Ni, which enables a wide ratio range achievement. A thin film of Gd-Ce oxidized after deposition and successfully transformed to crystallized GDC under a SOFC operation environment. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) confirmed its crystallinity, and the film deposited with various power ratios was sputtered on the ScSZ electrolyte pellet to clarify the optimum NiGDC ratio for thin-film SOFCs. Last, the Ni-GDC was applied to anodized aluminum oxide (AAO)-supported SOFCs to maximize the performance. The performance change according to the thickness of Ni-GDC was identified, and the best performance among them was 638 mW/cm2 at 500 degrees C.