Customizing the structure and chemical composition of ultralight carbon foams for superior microwave absorption performance

被引:63
|
作者
Cheng, Tingting [1 ]
Guo, Yuying [1 ]
Xie, Yuxin [1 ]
Zhao, Laibin [1 ]
Wang, Ting [2 ]
Meng, Alan [2 ]
Li, Zhenjiang [1 ]
Zhang, Meng [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Electromech Engn, Coll Mat Sci & Engn, Key Lab Polymer Mat Adv Mfg Technol Shandong Prov, Qingdao 266061, Shandong, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Gaomi Campus, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci,M, Qingdao 266042, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Ultralight; Porous carbon foam; Adjustable structure; Microwave absorption; Attenuation mechanism; NATURAL WOOD; CONSTRUCTION;
D O I
10.1016/j.carbon.2023.02.052
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing biomass-derived three-dimensional porous carbon materials (porous carbon foam, PCF) has become a common strategy to obtain lightweight and efficient electromagnetic microwave-absorbing materials. Without the introduction of a template and subsequent activation process, several ultra-lightweight honeycomb PCF samples were successfully prepared from dried ballonflower/yamakurage (DB) by simple calcination. In addi-tion, the calcination temperature plays a decisive role in regulating the pore size, composition and microwave absorption properties of PCF samples. Furthermore, it is worth noting that different cutting directions also influenced the hole size of the PCF sample and the microwave absorption performances. Under the combined effects of multiple reflections and scattering of PCF porous structure, dipole polarization of abundant hetero-geneous atoms and good conductive loss of carbon material, the vertical cutting sample PCF-900V exhibits optimal microwave absorption performances with the minimal reflection loss (RLmin) value of-46.95 dB at 1.46 mm thickness and the effective absorption bandwidth (EAB) value of 5.52 GHz at 1.72 mm matching thickness respectively, indicating its great potential for application as a promising lightweight and efficient microwave absorbing material.
引用
收藏
页码:181 / 191
页数:11
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