Improving the Cycling Stability of Aqueous Zinc-Ion Batteries by Preintercalation of Polyaniline in Hydrated Vanadium Oxide

被引：13
|
作者：
Khan, Muhammad Iftikhar [1 ,2 ]
Jia, Xiaoxiao [1 ]
Wang, Zhi [1 ]
Cao, Guozhong [1 ]
机构：
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Lahore, Dept Phys, Lahore 53700, Pakistan
来源：
ACS APPLIED MATERIALS & INTERFACES | 2023年 / 15卷 / 21期
基金：
美国国家科学基金会;
关键词：
polyaniline; aqueous zinc-ion batteries; intercalation; hydrated vanadium pentoxide; cycling stability; ELECTRODE MATERIALS; CRYSTAL-STRUCTURES; CATHODE MATERIALS; PERFORMANCE; CARBON; PENTOXIDE; INTERCALATION; NANOSHEETS; VANADATE; ARRAYS;
D O I：
10.1021/acsami.3c03530
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Thispaper reports the synthesis and characterization of hydratedvanadium oxide (VOH) and chemically preintercalated polyanilines inVOH, labeled as PAVO-H as the cathode material for aqueous zinc-ionbatteries. Synthesized PAVO-H has a high surface area and rod-shapedmorphology. PAVO-H has an increased interlayer distance of 13.36 & ANGS;.PAVO-H offers high specific capacities of 330 and 225 mAh g(-1) at 50 mA g(-1) and 4 A g(-1) ofcurrent densities, respectively, with a 92% capacity retention rateof over 3000 cycles. The preintercalation of polyaniline is likelyto catalyze the redox reaction and facilitate and simplify transportkinetics. It is also possible that the preintercalation of polyanilinepermits the insertion of large hydrated Zn ions and reduces the formationof zinc basic salts.
引用
收藏
页码：25980 / 25989
页数：10
相关论文
共 50 条
  • [1] Amorphous hydrated vanadium oxide with enlarged interlayer spacing for aqueous zinc-ion batteries
    Kim, Dong-Wan (dwkim1@korea.ac.kr), 1600, Elsevier B.V. (420):
  • [2] Amorphous hydrated vanadium oxide with enlarged interlayer spacing for aqueous zinc-ion batteries
    Ju, Bobae
    Song, Hee Jo
    Yoon, Hyunseok
    Kim, Dong-Wan
    CHEMICAL ENGINEERING JOURNAL, 2021, 420
  • [3] Ultralong cycle stability of aqueous zinc-ion batteries with zinc vanadium oxide cathodes
    Wang, Lulu
    Huang, Kuo-Wei
    Chen, Jitao
    Zheng, Junrong
    SCIENCE ADVANCES, 2019, 5 (10)
  • [4] Structural Engineering of Vanadium Oxide Cathodes by Mn2+ Preintercalation for High-Performance Aqueous Zinc-Ion Batteries
    Li, Fengfeng
    Sheng, Hongwei
    Ma, Hongyun
    Qi, Yifeng
    Shao, Mingjiao
    Yuan, Jiao
    Li, Wenquan
    Lan, Wei
    ACS APPLIED ENERGY MATERIALS, 2023, 6 (11) : 6201 - 6213
  • [5] Catalyzing zinc-ion intercalation in hydrated vanadates for aqueous zinc-ion batteries
    Liu, Chaofeng
    Tian, Meng
    Wang, Mingshan
    Zheng, Jiqi
    Wang, Shuhua
    Yan, Mengyu
    Wang, Zhaojie
    Yin, Zhengmao
    Yang, Jihui
    Cao, Guozhong
    JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (16) : 7713 - 7723
  • [6] Revealing the role of calcium ion intercalation of hydrated vanadium oxides for aqueous zinc-ion batteries
    Tao Zhou
    Xuan Du
    Guo Gao
    Journal of Energy Chemistry, 2024, 95 (08) : 9 - 19
  • [7] Revealing the role of calcium ion intercalation of hydrated vanadium oxides for aqueous zinc-ion batteries
    Zhou, Tao
    Du, Xuan
    Gao, Guo
    JOURNAL OF ENERGY CHEMISTRY, 2024, 95 : 9 - 19
  • [8] Zinc-Ion Storage Mechanism of Polyaniline for Rechargeable Aqueous Zinc-Ion Batteries
    Gong, Jiangfeng
    Li, Hao
    Zhang, Kaixiao
    Zhang, Zhupeng
    Cao, Jie
    Shao, Zhibin
    Tang, Chunmei
    Fu, Shaojie
    Wang, Qianjin
    Wu, Xiang
    NANOMATERIALS, 2022, 12 (09)
  • [9] Al3+ Introduction Hydrated Vanadium Oxide Induced High Performance for Aqueous Zinc-Ion Batteries
    Xu, Jing
    Zhang, Yu
    Liu, Chenfan
    Cheng, Huanhuan
    Cai, Xuanxuan
    Jia, Dianzeng
    Lin, He
    SMALL, 2022, 18 (47)
  • [10] Fundamental understanding of the proton and zinc storage in vanadium oxide for aqueous zinc-ion batteries
    Pan, Qing
    Dong, Ran
    Lv, Huizhen
    Sun, Xiaoqi
    Song, Yu
    Liu, Xiao-Xia
    CHEMICAL ENGINEERING JOURNAL, 2021, 419
12345