Building Smarter Aqueous Batteries

Amidst the global trend of advancing renewable energies toward carbon neutrality, energy storage becomes increasingly critical due to the intermittency of renewables. As an alternative to lithium-ion batteries (LIBs), aqueous batteries have received growing attention for large-scale energy storage due to their economical and safe features. Despite the fruitful achievements at the material level, the reliability and lifetime of aqueous batteries are still far from satisfactory. Alike LIBs, integrating smartness is essential for more reliable and long-life aqueous batteries via operando monitoring and automatic response to extreme abuses. In this review, recent advances in sensing techniques and multifunctional battery-sensor systems together with self-healing methods in aqueous batteries is summarized. The significant role of artificial intelligence in designing and optimizing aqueous batteries with high efficiency is also highlighted. Ultimately, it is extrapolated toward the future and present the humble perspective for building smarter aqueous batteries. Under the trend of achieving global carbon neutrality, aqueous batteries (ABs) are considered as promising candidates for clean energy storage. Herein, the importance of incorporating smartness into the research and development of ABs is highlighted in four aspects with relevant progress summarized. Prospective research directions are also provided in the end toward building smarter ABs.image