Fluorescent Bodipy Sensor for Trace Detection of Nerve Agents Simulant via Supramolecular Approach

被引:3
|
作者
Santonocito, Rossella [1 ]
Cavallaro, Alessia [1 ]
Puglisi, Roberta [1 ]
Intravaia, Manuelamaria [1 ]
Toscano, Rosa Maria [1 ]
Pappalardo, Andrea [1 ,2 ]
Sfrazzetto, Giuseppe Trusso [1 ,2 ]
机构
[1] Univ Catania, Dept Chem Sci, Viale A Doria 6, I-95125 Catania, Italy
[2] Natl Interuniv Consortium Mat Sci & Technol INSTM, Res Unit Catania, I-95125 Catania, Italy
关键词
Chemical warfare agents; smartphone; supramolecular sensing; bodipy; fluorescence; sensitivity; CHEMICAL WARFARE AGENTS; AMPHIPHILIC BASKETS; SELECTIVE DETECTION; RECOGNITION; COMPLEXES; SERIES; REMEDIATION; DERIVATIVES; BINDING; SARIN;
D O I
10.2174/1385272827666230828121210
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The use of organophosphorus (OP) Nerve Agents (NAs) as chemical weapons still represents a real danger for the safety of population threaten by conflicts or terrorist attacks. A fast and easy-to-use detection of this hazardous gases could make the difference in emergency state. Specifically, the possibility to develop a detection system involving an easily accessible tool, such as a smartphone, is the driving force of the current research work. Due to the great advantages related to the optical sensing, we here report two new BODIPY-based fluorescent receptors for Dimethyl methyl phosphonate (DMMP) NA simulant, with one of the lowest limit of detection. A solid sensor was then developed able to give an OFF/ON response to low ppm concentration of DMMP gas, by using a common smartphone camera with an integrated open-source processing software.
引用
收藏
页码:876 / 882
页数:7
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