The Benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole)-4-carbonitrile

被引：0

作者：

Chmovzh, Timofey N. ^{[1
,2
]}

Kudryashev, Timofey A. ^{[1
,3
]}

Gaisin, Karim S. ^{[1
,3
]}

Rakitin, Oleg A. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prospekt, Moscow 119991, Russia

[2] South Ural State Univ, Nanotechnol Educ & Res Ctr, 76 Lenina Ave, Chelyabinsk 454080, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

MOLBANK | 2023年 / 2023卷 / 03期

关键词：

sulfur-nitrogen heterocycles; benzo[1,2-d:4,5-d']bis([1,2,3]thiadiazole); cyanation; ELECTRON-DEFICIENT;

D O I：

10.3390/M1683

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electron-withdrawing heterocyclic units are found in most organic optoelectronic materials. Benzo[1,2-d:4,5-d']bis([1,2,3]thiadiazole) is an interesting new heterocyclic system, the chemical properties of which are much less studied than other fused thiadiazoles. Cyano derivatives of electron-accepting heterocycles are known as potential components of photoluminescent materials. In this communication, benzo[1,2-d:4,5-d']bis([1,2,3]thiadiazole)-4-carbonitrile was successfully obtained via the cyanation of 4-bromobenzo[1,2-d:4,5-d']bis([1,2,3]thiadiazole) with copper(I) cyanide in DMF. The structure of the newly synthesized compound was established by means of elemental analysis, high-resolution mass spectrometry, H-1 and C-13 NMR, and IR spectroscopy.

引用

页数：4

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