Mass spectrometry in organic and bio-organic catalysis: Using thermochemical properties to lend insight into mechanism

被引：0
|
作者：
Hinz, Damon J. [1 ]
Zhang, Lanxin [1 ]
Lee, Jeehiun K. [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, New Brunswick, NJ 08901 USA
来源：
MASS SPECTROMETRY REVIEWS | 2023年 / 42卷 / 05期
关键词：
acidity; enzymes; organocatalysts; proton affinity; reaction mechanisms; URACIL-DNA GLYCOSYLASE; GAS-PHASE ACIDITY; ASYMMETRIC ALLYLATION; PROTON AFFINITIES; INTRINSIC REACTIVITY; TRANSITION-STATE; HYDROGEN-BOND; N-OXIDE; ALDEHYDES; SITES;
D O I：
10.1002/mas.21797
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
In this review, we discuss gas phase experimentation centered on the measurement of acidity and proton affinity of substrates that are useful for understanding catalytic mechanisms. The review is divided into two parts. The first covers examples of organocatalysis, while the second focuses on biological catalysis. The utility of gas phase acidity and basicity values for lending insight into mechanisms of catalysis is highlighted.
引用
收藏
页码：1965 / 1983
页数：19
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