Photocatalyst-Free Visible-Light-Promoted C-H Selenylation of Pyrazolo[1,5-a ]pyrimidines

被引:3
|
作者
Sikdar, Papiya [1 ]
Choudhuri, Tathagata [1 ]
Paul, Suvam [1 ]
Das, Sourav [1 ]
Kumar, Anil [2 ]
Bagdi, Avik Kumar [1 ]
机构
[1] Univ Kalyani, Dept Chem, Kalyani 741235, India
[2] Birla Inst Technol & Sci Pilani, Dept Chem, Pilani 333031, Rajasthan, India
来源
SYNTHESIS-STUTTGART | 2023年 / 55卷 / 21期
关键词
photocatalyst-free; C-H selenylation; pyrazolo[1,5-a ]pyrimidine; persulfate; visible light; CATALYST; GREEN;
D O I
10.1055/a-2124-5485
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new method has been developed for the C-H selenylation of pyrazolo[1,5-a]pyrimidine derivatives under the irradiation of visible light. This photocatalyst-free strategy is applicable to a wide range of pyrazolo[1,5-a]pyrimidines with broad functionalities. The salient features of the method are mild reaction conditions, use of bench-stable oxidant, high regioselectivity, and scalability.
引用
收藏
页码:3693 / 3699
页数:7
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