Recent Progress in the Catalytic Synthesis of Pyrrolo[1,2-a]quinoxaline

被引:7
|
作者
Liu, Quan [1 ,2 ]
Wang, Wenquan [1 ,2 ]
Liu, Meng [1 ,2 ]
机构
[1] Shaanxi Univ Technol, Shaanxi Key Lab Catalysis, Hanzhong 723001, Peoples R China
[2] Shaanxi Univ Technol, Sch Chem & Environm Sci, Hanzhong 723001, Peoples R China
关键词
Pyrrolo[1,2-a]quinoxalines; Metal-catalysed; Bimetallic synergistic catalysis; Metal-free catalytic; Catalytic mechanism; ONE-POT SYNTHESIS; TRANSFER HYDROGENATION; ANTIMALARIAL ACTIVITY; EFFICIENT SYNTHESIS; BRONSTED ACID; DERIVATIVES; CYCLIZATION; REDUCTION; COPPER; NITROARENES;
D O I
10.1002/ajoc.202300277
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pyrrolo[1,2-a]quinoxaline and its derivatives have excellent biological activity and photoelectric properties, and are widely used in the fields of pharmaceutical preparations and organic electroluminescence. This review starts from catalysts and summarizes the single metal catalysis of palladium, rhodium, iron, molybdenum, and copper, as well as the synergistic catalysis of iron molybdenum bimetallic and metal-free catalytic systems for the synthesis of pyrrolo[1,2-a]quinoxaline. The pyrrolo[1,2-a]quinoxaline catalytic mechanism in the different catalytic systems was detailly introduced and analysed. By analysing the advantages and disadvantages of existing catalyst systems, the prospects of new catalysts and methods for synthesis of pyrrolo[1,2-a]quinoxaline are presented.
引用
收藏
页数:15
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