Colorless zinc colored by metal-metal orbital interaction

被引：0
|
作者：
Liu, Wei [1 ]
Zhang, Wen-Xiong [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Minist Educ,Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China
来源：
CHEM | 2023年 / 9卷 / 11期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
COMPLEXES;
D O I：
10.1016/j.chempr.2023.10.011
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Zn(II) complex is colorless, which is a common feature unless the complex is accompanied by chromophoric moieties. Recently in Angewandte Chemie International Edition, Wada et al. reported a dinuclear Zn(II) complex that bears two non-chromophoric oligo-silyl ligands and exhibits visible-light absorption. Their work intro-duces a strategy for constructing Zn-based complexes capable of responding to visible light and extends the photophysical field of zinc chemistry.
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收藏
页码：3027 / 3029
页数：3
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