Excess Molar Volumes and Viscosities of Binary Mixture of Diethyl Carbonate+Ethanol at Different Temperatures

被引:0
|
作者
马沛生
李楠楠
机构
[1] Tianjin 300072
[2] China
[3] School of Chemical Engineering and Technology
[4] Key Laboratory for Green Chemical Technology of Education Ministry of China
[5] Tianjin University
关键词
density; viscosity; excess molar volume; diethyl carbonate; ethanol;
D O I
暂无
中图分类号
TQ22 [脂肪族化合物(无环化合物)的生产];
学科分类号
0817 ;
摘要
The purpose of this work was to report excess molar volumes and dynamic viscosities of the binary mixture of diethyl carbonate (DEC)+ethanol. Densities and viscosities of the binary mixture of DEC+ethanol at temperatures 293.15 K—343.15 K and atmospheric pressure were determined over the entire composition range. Densities of the binary mixture of DEC+ethanol were measured by using a vibrating U-shaped sample tube densimeter. Viscosities were determined by using Ubbelohde suspended-level viscometer. Densities are accurate to 1.0×10-5 g·cm-3, and viscosities are reproducible within ±0.003 mPa·s. From these data, excess molar volumes and deviations in viscosity were calculated. Positive excess molar volumes and negative deviations in viscosity for DEC+ethanol system are due to the strong specific interactions.All excess molar vo-(lumes) and deviations in viscosity fit to the Redlich-Kister polynomial equation.The fitting parameters were presented,and the average deviations and standard deviations were also calculated.The errors of correlation are very small.It proves that it is valuable for estimating densities and viscosities of the binary mixture by the correlated equation.
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页码:101 / 105
页数:5
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