Water-stable ZIF-300/Ultrason? mixed-matrix membranes for selective CO2 capture from humid post combustion flue gas

Water stable mixed-matrix membranes(MMMs) were developed to help control the global warming by capturing and sequestrating carbon dioxide(CO) from post-combustion flue gas originated from burning of fossil fuels.MMMs of different compositions were prepared by doping glassy polymer Ultrason? S 6010(US) with nanocrystals of zeolitic imidazolate frameworks(ZIF-300) in varying degrees. Solution-casting technique was used to fabricate various MMMs to optimize their COcapturing performance from both dry and wet gases. The prepared composite membranes indicated enhanced filler-polymer interfacial adhesion, consistent distribution of nanofiller, and thermally established matrix configuration. COpermeability of the membranes was enhanced as demonstrated by gas sorption and permeation experiments performed under both dry and wet conditions. As compared to neat Ultrason? membrane, COpermeability of the composite membrane doped with 40 wt% ZIF-300 nanocrystals was increased by four times without disturbing CO/Nideal selectivity. In contrast to majority of previously reported membranes, key features of the fabricated MMMs include their structural stability under humid conditions coupled with better and unaffected gas separation performance.