TRINUCLEAR BASIC CARBOXYLATE COMPOUNDS OF TRANSITION METALS PART 2. SYNTHESIS AND CRYSTAL STRUCTURE OF [Fe3O （EtCO2）3（MeCO2）3（H2O）3]NO3·H2O

被引：0
|
作者：
Zhang Han-Hui Yu Xiu-FenFuzhou Laboratory of Structural Chemistry
机构：
来源：
Chinese Journal of Structural Chemistry | 1990年 / 01期
关键词：
Fe3O; SYNTHESIS AND CRYSTAL STRUCTURE OF; EtCO2; H2O; MeCO2; NO3; BASIC;
D O I：
10.14102/j.cnki.0254-5861.1990.01.002
中图分类号：
学科分类号：
摘要：
The title complex crystallizes in monoclinic system,space group C 2/m with α=19. 870(5),b=13. 070(2),c=18. 246(4)A ,β=134. 32(1)°,Mr = 707. 88, V=3390. 0A3.Z = 4,DC=1. 387g/cm3,F(000) = 1468,final R=0. 066 for 2244 independent reflections with Ⅰ >3σ(Ⅰ). The cation was shown to contain three Fe (Ⅲ) atoms at the apices of an equilateral triangle with a 3-O bridge.The Fe (1)-(μ3-O)and Fe(2)-(μ3-O) distances are 1. 907(6) and 1. 87(1) A , respectively. And mixed ligands of acetato and propionyloxy lato are bridged to each pair of the Fe(Ⅲ) atoms.
引用
收藏
页码：6 / 9
页数：4
相关论文
共 50 条
  • [1] TRINUCLEAR BASIC CARBOXYLATE COMPOUNDS OF TRANSITION METALS PART 1. SYNTHESIS AND CRYSTAL STRUCTURE OF {Fe2MnO（EtCO2）5（H2O）4}·NO3
    Zhang Han-Hui Yu Xiu-FenFuzhou Laboratory of Structural Chemistry
    [J]. Chinese Journal of Structural Chemistry, 1990, (01) : 1 - 5
  • [2] Intermediate frustration in [Fe3O(CH3COO)6(H2O)3] NO3 • 4(H2O) trinuclear cluster
    Filoti, G
    Bartolome, J
    Dickson, DPE
    Rillo, C
    Prisecaru, I
    Jovmir, T
    Kuncser, V
    Turta, C
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 196 : 561 - 563
  • [3] Cyclic voltammetric study of the trinuclear complexes [Fe3O(CH3COO)6(H2O)3]NO3 and [Fe3O(+H3NCH2COO-)6(H2O3]NO3)7
    Storch, H
    Constantinescu, E
    Andrei, M
    Dima, G
    Turta, C
    Lazarescu, A
    [J]. REVUE ROUMAINE DE CHIMIE, 2002, 47 (1-2) : 67 - 70
  • [4] Structural transition at 225 K of the trinuclear Fe(III) heptanoate [Fe3O(O2CC6H13)6(H2O)3]NO3
    François, M
    Saleh, MI
    Rabu, P
    Souhassou, M
    Malaman, B
    Steinmetz, J
    [J]. SOLID STATE SCIENCES, 2005, 7 (10) : 1236 - 1246
  • [5] THE CRYSTAL-STRUCTURE OF THE COMPLEX [Y(H2O)5(NO3)2] [Y(H2O)2(NO3)4]
    RADIVOJEVIC, P
    MILINSKI, N
    RIBAR, B
    LAZAR, D
    [J]. CROATICA CHEMICA ACTA, 1984, 57 (04) : 451 - 455
  • [6] REINVESTIGATION OF THE STRUCTURE OF [Y(H2O)5(NO3)2][Y(H2O)2(NO3)4]
    RIBAR, B
    KAPOR, A
    SCOTT, B
    WILLETT, RD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1993, 49 : 314 - 316
  • [7] Solubility Modeling of the Binary Systems Fe(NO3)3–H2O, Co(NO3)2–H2O and the Ternary System Fe(NO3)3–Co(NO3)2–H2O with the Extended Universal Quasichemical (UNIQUAC) Model
    Mouad Arrad
    Mohammed Kaddami
    Bahija El Goundali
    Kaj Thomsen
    [J]. Journal of Solution Chemistry, 2016, 45 : 534 - 545
  • [8] CRYSTAL, MOLECULAR, AND ELECTRONIC-STRUCTURE OF CARBOXYLATE [FE3O(CH3COO)6(H2O)3]NO3.4H2O
    TURTE, KI
    SHOVA, SG
    SPATAR, FA
    MAZUS, MD
    MALINOVSKII, TI
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1994, 35 (02) : 248 - 255
  • [9] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3 [α-P2W17Fe(H2O)O61]·32.5H2O
    N. V. Izarova
    M. N. Sokolov
    A. V. Virovets
    H. G. Platas
    V. P. Fedin
    [J]. Journal of Structural Chemistry, 2005, 46 : 147 - 153
  • [10] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3[α-P2W17Fe(H2O)O61]•32.5H2O
    Izarova, NV
    Sokolov, MN
    Virovets, AV
    Platas, HG
    Fedin, VP
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (01) : 147 - 153
12345