Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes

被引：2

作者：

Bin Wang ^{[1
]}

Hui Yang ^{[1
]}

Ya-Bo Xie ^{[1
]}

Yi-Bo Dou ^{[1
]}

Min-Jian Zhao ^{[1
]}

Jian-Rong Li ^{[1
]}

机构：

[1] Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology

来源：

Chinese Chemical Letters | 2016年 / 27卷 / 04期

关键词：

Metal-organic frameworks(MOFs); Design and synthesis; Crystal structure; Tuned topological network;

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

Two new metal-organic frameworks（MOFs）,[Cu2（H;O）;（BCPIA）]（BUT-20）and（Me;NH;）[In（BCPIA）]（BUT-21）were designed and synthesized through the solvothermal reaction between a newly created desymmetric 4-connected ligand,5-(2,6-bis（4-carboxyphenyl）pyridin-4-yl)isophthalic acid（H;BCPIA）and Cu（NO;）2 2.5H;O or In（NO;）;·5H;O,respectively,and characterized by single-crystal and powder Xray diffraction,thermogravimetric analysis,infrared spectroscopy,and elemental analysis.The two MOFs have three-dimensional structures,in which both the BCPIA 4 ligand and metal-containing entities,Cu;（COO）;（H;O）;and In（COO）;act as 4-connected nodes.However,different linkage configurations of the two metal-containing nodes,quadrilateral Cu;D;（COO）;（H;O）;and tetrahedral In（COO）;,lead to distinct structural networks of BUT-20 and 21,with Nbo and Unc topologies,respectively.

引用

页码：502 / 506

页数：5

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