STATISTICAL THERMODYNAMICS OF POLYMER MIXTURES

被引：0
|
作者：
柴志宽
机构：
[1] Institute of Chemistry
[2] Beijing
[3] Academia Sinica
来源：
Science in China,SerB. | 1988年 / Ser.B.1988卷 / 06期
基金：
中国国家自然科学基金;
关键词：
In; STATISTICAL THERMODYNAMICS OF POLYMER MIXTURES;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Based on a hole model the equation of state of polymeric liquids, the chemical poten-tial and the spinodal of polymer mixtures are derived. In the model the volume changesof liquids are realized through changing the distance between molecules (size of the cell)and number of holes in liquids. If these two factors are considered one by one, two setsof equations of the above equilibrium properties are obtained but one common chemicalpotential equation. With further simplification all the formulas are reduced to that of theFlory or the Sanchez theory respectively.
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页码：660 / 666
页数：7
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