A Cadmium（II） Coordination Polymer: Crystal Structure and Fluorescent Property of [CdCl2（4,4'-bipyridine）] ∞

被引：0
|
作者：
LOU Ben-Yong WANG Rui-Hu XU Ying YUAN Da-Qiang ZHOU You-Fu HONG Mao-Chun② (State Key Laboratory of Structural Chemistry
机构：
来源：
Chinese Journal of Structural Chemistry | 2004年 / 07期
基金：
中国国家自然科学基金;
关键词：
cadmium(Ⅱ); coordination polymer; crystal structure; fluorescence;
D O I：
10.14102/j.cnki.0254-5861.2004.07.007
中图分类号：
O631 [高分子物理和高分子物理化学];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The reaction of L-histidine, CdCl22.5H2O and 4,4-bipyridine in methane/water gave rise to a two-dimensional coordination polymer [CdCl2(4,4-bipyridine)] which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in the orthorhombic sys- tem, space group Cmmm with a = 12.083(7), b = 11.771(7), c = 3.781(2) ? V = 537.8(6) ?, Z = 2, C10H8N2CdCl2, Mr = 339.48, Dc = 2.097 g/cm3, F(000) = 328 and (MoK? = 2.490 mm-1. The final R = 0.0658 and wR = 0.1398 for 257 observed reflections with I≥2(I).
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页码：747 / 750
页数：4
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