EXTENSIONAL FLOW OF BULK POLYMERS STUDIED BY DYNAMIC MONTE CARLO SIMULATIONS附视频

Dynamic Monte Carlo simulations of bulk lattice polymers driven through planar geometries with sequentially converging,parallel and diverging spaces between two neutrally repulsive solid plates are reported.The spatial profiles of polymer velocity and deformation along the course of such a laminar extensional flow have been carefully analyzed.The results appear consistent with experimental observations in literature.In the entrance and exit regions,a linear dependence of chain extension upon the excess velocity has been observed.Moreover,an annexed shear flow and a molecular-dispersion effect are found.The results demonstrate a useful strategy of this approach to study polymer flows and bring new insights into the non-Newtonian-fluid behaviors of bulk polymers in capillary rheometers and micro-fluidic devices.