Construction of Supramolecular Architectures via Self-assembly

被引：0

作者：

Takeharu Haino

机构：

[1] 1-3-1 Kagamiyama

[2] Deparment of Chemistry Graduate School of Science

[3] Higashi-Hiroshima City739-8526

[4] Hiroshima University

[5] Japan

来源：

复旦学报(自然科学版) | 2007年 / 05期

关键词：

fullerene; calixarene; supramolecular chemistry; host-guest complex;

D O I：

10.15943/j.cnki.fdxb-jns.2007.05.084

中图分类号：

O631.3 [高聚物的化学性质];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

1 Results In this paper we report supramolecular polymeric nano networks formed by the molecular-recognition-directed self-assembly between a calix[5]arene and C60[1]. Covalently-linked double-calix[5]arenes take up C60 into their cavities[2]. This complementary interaction creates a strong non-covalent bonding; thus,the iterative self-assembly between dumbbell fullerene 1 and ditopic host 2 can produce the supramolecular polymer networks (See Fig.1).

引用

页码：643 / 643

页数：1