A New Two-dimensional Cd(Ⅱ) Complex Assembled by 1,3,5-Benzenetricarboxylic Acid and 3-(2-Pyridyl)pyrazole

被引：6
|
作者：
王秀艳 [1 ]
李秀梅 [2 ]
潘亚茹 [2 ]
刘博 [1 ]
周实 [1 ]
机构：
[1] Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education
[2] Faculty of Chemistry, Tonghua Normal University
来源：
Chinese Journal of Structural Chemistry | 2019年 / 38卷 / 08期
关键词：
coordination polymer; synthesis; crystal structure; cadmium complex; natural bond orbital;
D O I：
10.14102/j.cnki.0254-5861.2011-2220
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
摘要：
A new 2D coordination polymer, {[Cd;（BTC）;（L）;（H;O）;];·2H;O};(1, H;BTC = 1,3,5-benzenetricarboxylic acid, HL = 3-（2-pyridyl）pyrazole) was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA, fluorescence spectrum and elemental analysis techniques. Complex 1 belongs to the monoclinic system, P2;space group, with a = 8.8732（4）, b = 17.5179（7）, c = 17.8123（7） ?, β = 103.1830（10）°, V = 2695.77（19） ?;and Z = 2. It features a 2D network constructed by BTC and L ligand. In addition, we analyzed Natural Bond Orbital（NBO） by using the PBE0/LANL2DZ method built in Gaussian 09 Program. The calculation results indicated obvious covalent interactions between the coordinated atoms and Cd（Ⅱ） ion.
引用
收藏
页码：1275 / 1282
页数：8
相关论文
共 50 条
  • [1] A New Two-dimensional Cd(II) Complex Assembled by 1,3,5-Benzenetricarboxylic Acid and 3-(2-Pyridyl)pyrazole
    Wang Xiu-Yan
    Li Xiu-Mei
    Pan Ya-Ru
    Liu Bo
    Zhou Shi
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (08) : 1275 - 1282
  • [2] A new heterometallic Cu(II)-Cd(II) complex based on 1,3,5-benzenetricarboxylic acid
    Sun, Qiao-Zhen
    Pan, Jun-Qiao
    Chai, Li-Yuan
    Zhang, Bing-Guang
    Liu, Na-Wei
    Liu, Hui
    INORGANIC AND NANO-METAL CHEMISTRY, 2018, 48 (03) : 165 - 169
  • [3] CRYSTAL STRUCTURE OF ERBIUM(Ⅲ) COMPLEX WITH 1,3,5-BENZENETRICARBOXYLIC ACID
    Duan Zhi-Bang Jin Zhong-Sheng Wei Ge-Cheng Ni Jia-Zan Changchun Institute of Applied Chemistry
    结构化学, 1990, (01) : 64 - 68
  • [4] SYNTHESIS AND CRTYSTAL STRUCTURE OF LUTETIUM (Ⅲ) COMPLEX WITH 1,3,5-BENZENETRICARBOXYLIC ACID
    Duan Zhi-Bang Wei Ge-Cheng Jin Zhong-Sheng Ni Jia-ZanChangchun Institute of Applied Chemistry
    结构化学, 1992, (05) : 347 - 350
  • [5] Solubility of 1,3,5-Benzenetricarboxylic Acid in Different Solvents
    Zhang, Dan
    Xu, Qian
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (02): : 1003 - 1006
  • [6] ZnII and CuII-Based Coordination Polymers and Metal Organic Frameworks by the of Use of 2-Pyridyl Oximes and 1,3,5-Benzenetricarboxylic Acid
    Mylonas-Margaritis, Ioannis
    Mayans, Julia
    McArdle, Patrick
    Papatriantafyllopoulou, Constantina
    MOLECULES, 2021, 26 (02):
  • [7] The Study and Characterization of a Novel Structure of 1,3,5-Benzenetricarboxylic Acid
    Tan, HaiYan
    Liu, Cheng
    Wu, JinPing
    ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY, BIOINFORMATICS III, 2014, 830 : 202 - 206
  • [8] Safer conditions for the Curtius rearrangement of 1,3,5-benzenetricarboxylic acid
    Davis, Matthew C.
    SYNTHETIC COMMUNICATIONS, 2007, 37 (19-21) : 3519 - 3528
  • [9] Two Metal Ion-controlled Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on 1,3,5-Benzenetricarboxylic Acid
    王记江
    曹壮
    唐龙
    王潇
    侯向阳
    鞠萍
    张恩生
    结构化学, 2017, 36 (10) : 1617 - 1623
  • [10] Crystal Structure of a Metallohybrid Acid of 1,3,5-Benzenetricarboxylic Acid of Copper(II)
    Kusum Bania
    Nilotpal Barooah
    Rupam Sarma
    Jubaraj Bikash Baruah
    Journal of Chemical Crystallography, 2008, 38 : 57 - 60
12345