Effect of CeO2 on carbon deposition resistance of Ni/CeO2 catalyst supported on SiC porous ceramic for ethanol steam reforming

Ni/CeO2catalysts(nCeO2:nNi=0,1,4,7,10) supported on SiC porous ce ramics for ethanol steam reforming(ESR) were investigated with respect to hydrogen production performance and growth of carbon deposition.The oxygen released from CeO2enables the oxidation of CHxspecies to serve as carbon precursors,thus providing Ni/CeO2catalysts with stronger resistance to carbon deposition compared with Ni catalysts.The Ni/CeO2catalysts prepared by inverse microemulsion and impregnation methods exhibit regular semicircular spherical shape on SiC porous ceramics.Under 500℃ for 25 h of ESR reaction,the ethanol conversion rate over Ni/CeO2catalysts(nCeO2:nNi=7) is sustained up to 100% and H2selectivity is essentially kept at 74%.The by-product selectivity declines stepwise with increasing content of CeO2,which is attributed to the adsorption and oxidation of CO and of CHxspecies as CH4precursor from CeO2.The scanning electron microscopy(SEM) and transform electron microscopy(TEM) results reveal that further loading of CeO2on the surface of Ni catalysts can alleviate both migration and sintering of Ni particles.Furthermore,carbon deposition on Ni/CeO2catalysts preferentially outgrow filamentous rather than amorphous carbon,with a tendency for the latter to be more deactivated.