Supramolecular Architecture from the Self-assembly of One-dimensionalCoordination Polymers and Hydrogen Bonds

被引:0
|
作者
Chun Hua GE1
机构
关键词
Crystallization; coordination polymer; supramolecular chemistry;
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暂无
中图分类号
O631 [高分子物理和高分子物理化学];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The novel one-dimensional coordination polymer {[Cu(L)2(H2O)]?2BF4?6H2O}∞ [1, L=1,2-bis(4-pyridinecarboxamido)ethane] was synthesized as single crystals and characterized by means of X-ray diffraction analysis, elemental analysis, IR spectroscopy and TG measurement. Structure 1 consists of looped chains. In addition, linked by hydrogen bonds, the one-dimensional chains were transformed into three-dimensional framework, which shows channels filled with anions and uncoordinated water molecules.
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页码:183 / 186
页数:4
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