Stereodynamics of the O(~3P) with H2(D2) (ν=0,j=0) reaction

被引：1
|
作者：
刘玉芳 [1 ]
和小虎 [1 ]
施德恒 [1 ]
孙金锋 [1 ]
机构：
[1] Department of Physics,Henan Normal University
来源：
Chinese Physics B | 2011年 / 20卷 / 07期
基金：
中国国家自然科学基金;
关键词：
quasi-classical trajectory method; O+H 2 reaction; reaction cross section; vector correlation;
D O I：
暂无
中图分类号：
O643.1 [化学动力学];
学科分类号：
070304 ; 081704 ;
摘要：
Quasi-classical trajectory theory is used to study the reaction of O(3 P) with H 2 (D 2) based on the ground 3 A″ potential energy surface (PES).The reaction cross section of the reaction O+H 2 →OH+H is in excellent agreement with the previous result.Vector correlations,product rotational alignment parameters P 2 (j · k) and several polarizeddependent differential cross sections are further calculated for the reaction.The product polarization distribution exhibits different characteristics that can be ascribed to different motion paths on the PES,arising from various collision energies or mass factors.
引用
收藏
页码：481 / 486
页数：6
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