The main constituents of interstellar molecules are ~1, H12C,14N,16O32S,28Si.Within them ,only14N nucleus has a quadrupole moment.Therefore the spectra of the interstellar molecules with constituent14N havethe nuclear quadrupole hyperfine splittings which could be resolved by virtueof the advanced techniques in some sources.Measurement of the ratios(R)of the hyperfine(hf)satellite intensities(I)offers important astrophysicalinformations. If the excitation temperatures of the hyperfine satellites are