SYNTHESIS AND STRUCTURE OF HEXAKIS CDI-μ-（4-CHLORO-BENZYLTHIO ） NICKEL ] TRITETRACHLOROMETHANE SOL-VATE, [Ni（SCH2C6H4Cl-p）2]6 · 3CC14

被引：0
|
作者：
Cai Jin-Hua Rang Bei-ShengState Key Laboratory of Structural Chemistry and Fujian Institute of Research an the Structureof Matter
机构：
来源：
结构化学 | 1993年 / 05期
关键词：
Crystal Structure Synthesis Chloro-benzylthio-Nickel Complex;
D O I：
10.14102/j.cnki.0254-5861.1993.05.015
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学科分类号：
摘要：
CHClNiS, Mr = 2551. 62, monoclinic, space group C2/c, crystal data: a = 30. 322（5）, b=14. 168（3）, c=26. 453（4） A ,β=101. 00（4）°, V = 11155. 6 A3, Z=4, Dx=1. 519 g/cm3, λ（MoKα） = 0. 71069 A ,μ=17. 370 cm-1, F（000） = 5152, T = 293 K, final R = 0. 078, Rw = 0. 086 for 5610 (I>3σ（I）) reflections. The crystal is composed of discrete [Ni （SCH2C6H4Cl-p）2]6 and CCl4 solvent molecules. The coordination geometries of the Ni atoms are perfect planes sharing S...S edges. The six NiS4 squares are linked with each other forming a hexagonal prism. The p-ClC6H4CH2S- side chains in the molecule are arranged in the axial and equatorial positions alternately with respect to the pseudo-hexagonal axis of the molecule.
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页码：397 / 400
页数：4
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