Syntheses and Characterizations of Two New Coordination Polymers Based on Dicarboxylate and Nitrogen-contained Mixed Ligands

被引：0
|
作者：
于玲玲 [1 ]
机构：
[1] Weihai Vocational College,Department of Biology Chemistry Engineering
来源：
Chinese Journal of Structural Chemistry | 2011年 / 30卷 / 12期
关键词：
hydrothermal synthesis; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2011.12.016
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new carboxylate coordination polymers [Ni(2,3’-oba)(bib)]n] and [Mn(2,4’-oba)(bib)0.5]n(2,3’-oba = 2-(3-carboxyphenoxy)benzoic acid,2,4’-oba = 2-(4-carboxyphenoxy) ben-zoic acid and bib = 1,4-bis(2-methyl-imidazol-yl)butane) have been synthesized and characterized by elemental analysis,IR and X-ray single-crystal diffraction studies.Compound 1 crystallizes in monoclinic,space group P21/c,while compound 2 in the triclinic space group P.Compound 1 displays a one-dimensional ladder-like chain.The dinuclear paddle-wheel secondary building units(SBUs) constructed by four 2,4’-oba2-ligands in compound 2 are linked by bib into a 2D(4,4) layer structure.
引用
收藏
页码：1725 / 1730
页数：6
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