A theoretical analysis and its application of the second order EC' reactions at microelectrodes under steady-state conditions

被引：0

作者：

ZHUANG

机构：

来源：

Chinese Journal of Chemistry | 1993年 / 04期

关键词：

der; A theoretical analysis and its application of the second order EC; reactions at microelectrodes under steady-state conditions;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

With a new approach,the general current expressions of two typical second ordercatalytic reactions are obtained for disk,hemispherical and spherical microelectrodes understeady-state conditions.This approach is based on the concept of reaction layer.For thesecond order EC’ reactions,we also discussed how it is possible to observe pseudo-first orderor second order behavior.This consideration allows the study of the fast chemical reactionsand systems where the bulk concentrations of the reactants are nearly equal.Regenerationof Fe（EDTA） with HOwas selected as an example of a rapid catalytic reaction.

引用

页码：308 / 315

页数：8

共 50 条

[1] The application of the concept of reaction layer to the study of electrode processes coupled with the second-order chemical reactions at microelectrodes under steady-state conditions
Zhuang, QK
Sun, DD
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 440 (1-2) : 103 - 109
[2] THE APPLICATION OF THE CONCEPT OF THE STEADY-STATE REACTION DIFFUSION LAYER TO A STUDY OF THE ELECTRODE PROCESSES WITH MULTISTEP REACTIONS AT MICROELECTRODES UNDER STEADY-STATE CONDITIONS
ZHUANG, QK
CHEN, HY
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 346 (1-2) : 29 - 51
[3] A NEW APPROACH TO THE EQUATIONS FOR THE STEADY STATE CURRENTS AT MICROELECTRODES:EC'PROCESSES(SECOND ORDER REACTION)
Qian Kun ZHUANG
Hong Yuan CHEN Department of Chemistry
[J]. Chinese Chemical Letters, 1992, (09) : 723 - 726
[4] The kinetic study of multistep electrode processes at microelectrodes under steady-state conditions
Zhuang, QK
Chen, HY
[J]. ACTA CHIMICA SINICA, 1996, 54 (08) : 807 - 812
[5] THE GENERAL-CHARACTERISTICS OF MICROELECTRODES OF ANY PLANAR GEOMETRY UNDER STEADY-STATE CONDITIONS
LIU, XP
LU, JT
CHA, CS
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 295 (1-2): : 15 - 23
[6] 2ND-ORDER KINETICS FOR STEADY-STATE EC' REACTIONS AT A DISC MICROELECTRODE
TUTTY, OR
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 377 (1-2): : 39 - 51
[7] Steady-state analysis of second-order traffic models and application to traffic flow control
Sau, J.
Monteil, J.
Billot, R.
El Faouzi, N-E.
[J]. TRANSPORTMETRICA B-TRANSPORT DYNAMICS, 2019, 7 (01) : 1444 - 1466
[8] Microring electrode: Transient and steady-state chronoamperometric current for first-order EC reactions
Rajendran, L.
[J]. ELECTROCHIMICA ACTA, 2006, 51 (21) : 4439 - 4446
[9] Steady-state currents at inlaid and recessed microdisc electrodes for first-order EC′ reactions
Galceran, J
Taylor, SL
Bartlett, PN
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 476 (02): : 132 - 147
[10] THE CURRENT NEAR THE EDGE OF A MICROELECTRODE FOR STEADY-STATE EC' REACTIONS
TUTTY, OR
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 379 (1-2): : 519 - 521

← 1 2 3 4 5 →