Synthesis, Structure and Near-infrared Luminescence of a Dinuclear Ytterbium(Ⅲ) Complex with a Bis(2,2'-bipyridyl) Ligand

被引：0
|
作者：
徐海兵 [1 ]
谢在来 [1 ]
张礼仪 [1 ]
陈忠宁 [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2009年 / 11期
关键词：
crystal structure; NIR luminescence; ytterbium(III); energy transfer;
D O I：
10.14102/j.cnki.0254-5861.2009.11.018
中图分类号：
O621.13 [];
学科分类号：
070303 ; 081704 ;
摘要：
The title complex {Yb(hfac)3}2(bpyC≡CC6H4C≡Cbpy) (hfac = hexafluoroacetyl- acetonate,bpyC≡CC6H4C≡Cbpy=2-(pyridin-2-yl)-5-(2-(4-(2-(6-(pyridin-2-yl)pyridin-3-yl)ethynyl)- phenyl)ethynyl)pyridine) has been prepared and characterized by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with a = 17.240(16), b = 25.64(2), c = 16.481(15) , β = 93.469(9)°, V = 7271(12) 3, Z = 4, Mr = 2022.91, F(000) = 3888, Dc = 1.848 g/cm3 and μ(MoKα) = 2.708 mm–1. The structure was refined to R = 0.0714 and wR = 0.1762 for 9771 observed reflections (I > 2σ(I)). Sensitized near-infrared (NIR) luminescence from YbIII centers was achieved through efficient antenna effect or energy transfer from the bridging ligand chromophore.
引用
收藏
页码：1470 / 1474
页数：5
相关论文
共 50 条
  • [1] Synthesis, Structure and Near-infrared Luminescence of a Dinuclear Ytterbium(Ⅲ) Complex with a Bis(2,2'-bipyridyl) Ligand
    徐海兵
    谢在来
    张礼仪
    陈忠宁
    [J]. 结构化学, 2009, 28 (11) : 1470 - 1474
  • [2] Synthesis, Structure and Near-infrared Luminescence of a Dinuclear Ytterbium(III) Complex with a Bis(2,2′-bipyridyl) Ligand
    Xu Hai-Bing
    Xie Zai-Lai
    Zhang Li-Yi
    Chen Zhong-Ning
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (11) : 1470 - 1474
  • [3] Synthesis and Crystal Structure of Bis-(2,2' bipyridyl)-2-pyrimidinethiolate-Ni(Ⅱ) Complex
    CHEN Yan-Dan ZHANG Li-Yi CHEN Zhong-Ning② (State Key Laboratory of Structural Chemistry
    [J]. Chinese Journal of Structural Chemistry, 2003, (02) : 179 - 181
  • [4] SYNTHESIS, CRYSTAL STRUCTURE AND LUMINESCENT PROPERTY OF A DINUCLEAR Tb(II) COMPLEX WITH HOMOPHTHALIC ACID AND 2,2 '-BIPYRIDYL
    Wang, Li-Hua
    [J]. SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2015, 16 (02): : 179 - 183
  • [5] Synthesis and crystal structure of bis-(2,2′-bipyridyl)-2-pyrimidinethiolate-Ni(II) complex
    Chen, YD
    Zhang, LY
    Chen, ZN
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (02) : 179 - 181
  • [6] A magnesium complex containing a reduced 2,2′-bipyridyl ligand: Synthesis, structure, reactivity, and computational studies
    Ren, Wenshan
    Fang, Xiaojun
    Sun, Wenyan
    Gu, Defa
    Yu, Yang
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 842 : 47 - 53
  • [7] Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand
    Ren, Wenshan
    Zi, Guofu
    Walter, Marc D.
    [J]. ORGANOMETALLICS, 2012, 31 (02) : 672 - 679
  • [8] A 2,2'-bipyridyl calcium complex: synthesis, structure and reactivity studies
    Wu, Lingfeng
    Wang, Zhenghui
    Liu, Yumiao
    Chen, Liang
    Ren, Wenshan
    [J]. DALTON TRANSACTIONS, 2023, 52 (21) : 7175 - 7181
  • [9] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A BIS(2,2'-BIPYRIDYL)-TRITHIONATOCOPPER(II) COMPLEX
    FERRARI, MB
    FAVA, GG
    PELIZZI, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (01) : 8 - 9
  • [10] 2,2'-BIPYRIDYL-BIS[BIS(TRIMETHYLSILYL)METHYL]ZINC - SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION AND STRUCTURE
    WESTERHAUSEN, M
    RADEMACHER, B
    SCHWARZ, W
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (03) : 275 - 287
12345