Hydrothermal Synthesis and Crystal Structure of a Zinc（II） Polymer with a Two-dimensional Layer Structure: [Zn（pzdc）(phen)]n·nH2O

被引：0

作者：

李秀梅 ^{[1
]}

王志涛 ^{[1
]}

刘博 ^{[2
]}

王庆伟 ^{[2
]}

周实 ^{[2
]}

机构：

[1] Department of Chemistry, Tonghua Teachers College

[2] Department of Chemistry, Jilin Normal University

来源：

Chinese Journal of Structural Chemistry | 2009年 / 10期

关键词：

coordination polymer; hydrothermal synthesis; crystal structure; luminescence;

D O I：

10.14102/j.cnki.0254-5861.2009.10.008

中图分类号：

O631.3 [高聚物的化学性质];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A metal-organic coordination compound formulated as [Zn(pzdc)(phen)]n·nH2O 1 (H2pzdc = pyrazine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21/n with a = 11.607(2), b = 11.719(2), c = 13.140(3) , β = 110.707(3)o, V = 1671.9(6) 3, C18H12ZnN4O5, Mr = 429.69, Dc = 1.707 g/cm3, μ(MoKα) = 1.511 mm?1, F(000) = 872, Z = 4, the final R = 0.0356 and wR = 0.0853 for 2713 observed reflections (I > 2σ(I)). It exhibits an interesting two-dimensional layer structure and shows yellow photoluminescent property at room temperature.

引用

页码：1257 / 1260

页数：4

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