Hollow Bio-derived Polymer Nanospheres with Ordered Mesopores for Sodium-Ion Battery

被引：0

作者：

Yan Ai ^{[1
]}

Yuxiu You ^{[2
]}

Facai Wei ^{[1
]}

Xiaolin Jiang ^{[1
]}

Zhuolei Han ^{[1
]}

Jing Cui ^{[1
]}

Hao Luo ^{[1
]}

Yucen Li ^{[1
]}

Zhixin Xu ^{[3
]}

Shunqi Xu ^{[4
]}

Jun Yang ^{[3
]}

Qinye Bao ^{[1
]}

Chengbin Jing ^{[1
]}

Jianwei Fu ^{[5
]}

Jiangong Cheng ^{[6
]}

Shaohua Liu ^{[1
,6
]}

机构：

[1] State Key Laboratory of Precision Spectroscopy and Department of Materials, School of Physics and Electronic Science, East China Normal University

[2] School of Materials Science and Engineering, Zhengzhou University

[3] Center for Advancing Electronics Dresden (cfaed) and Department of Chemistry and Food Chemistry, Technische Universit?t Dresden

[4] Department of Physics and Astronomy, Shanghai Jiao Tong University

[5] State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences

[6] School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University

来源：

Nano-Micro Letters | 2020年 / 03期

关键词：

Self-assembly; Biomimetic synthesis; Mesoporous polymer; Ferric phytate; Sodium-ion battery;

D O I：

暂无

中图分类号：

TB383.1 []; TM912 [蓄电池];

学科分类号：

070205 ; 080501 ; 0808 ; 1406 ;

摘要：

Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of～12 nm,high surface area of 401 m~2 g,and large pore volume of 0.5 3 cm~3 g.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh gat 50 mA g,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.

引用

页码：5 / 15

页数：11

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