SYNTHESIS AND CHARACTERIZATION OF LIQUID CRYSTAL POLYMERS WITH T-SHAPED TWO-DIMENSIONAL MESOGENIC UNITS (Ⅱ)

被引:0
|
作者
李自法
郑世军
张淑媛
曹少魁
李磊
刘广胜
周其凤
机构
[1] Beijing 100871
[2] Chem. Dept.
[3] Mater. Eng. Dept.
[4] Peking Univ.
[5] Zhengzhou 450052
[6] Zhengzhou Univ.
基金
中国国家自然科学基金;
关键词
T-shaped two-dimensional mesogenic units; Liquid crystal polymer; Polymer synthesis;
D O I
暂无
中图分类号
O631 [高分子物理和高分子物理化学];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of liquid crystalline polymers with T-shaped two-dimensional mesogenic unitswere synthesized via low temperature solution polycondensation of 2-(4’-alkoxy-phenyl)hydroquinone with various diacyl dichlorides. The polymers were found to be nematic andshown thermotropic liquid crystalline behaviors through observations using DSC, polarizedmicroscopy and X-ray diffraction. The melting temperature T;and the isotropizationtemperature T;of the polymers change regularly with varying of the monomer structures.
引用
收藏
页码:65 / 73
页数:9
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