Fabrication of Ormocer Containing Eu3+ Ion and Their Optical Spectra

被引:0
|
作者
夏海平
宋宏伟
章践立
王金浩
聂秋华
张家骅
机构
[1] Key Laboratory of Excited State Physics
[2] Chinese Academy of Sciences Ningbo 315211
[3] China
[4] Chinese Academy of Sciences
[5] Changchun Institute of Optics
[6] Key Laboratory of Photo Electronic Materials
[7] Fine Machine and Physics
[8] Changchun 130021
[9] Ningbo University
关键词
organic chemistry; Eu 3+ ion; ormocer; optical spectra; rare earths;
D O I
暂无
中图分类号
O482.31 [发光学];
学科分类号
摘要
Eu 3+ ions were incorporated in sol and gel by a sol gel processing using 3 glycidoxypropyltrimethoxysilane (CH 2OCHCH 2O(CH 2) 3Si(OCH 3) 3, GPTMS) and ethyl silicate (TEOS) as precursors. The basic chemical physical properties such as DTA curve, FT IR spectra and specific surface area were recorded. The characteristics of their optical spectra were measured and investigated. The results indicate that the emission intensity of Eu 3+ ion in ormocer is much higher and the global line width is wider than those in SiO 2 gel. The relationship between the composition and structure of gels and the fluorescence intensity and width were discussed. The obtained ormocer shows good mechanical strength, which can be cut and polished in machine without broken.
引用
收藏
页码:318 / 321 +297
页数:5
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